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Unit 4 Chpt 12, 13, and 14 Review

True/False
Indicate whether the statement is true or false.
 

 1. 

Forces that act between two molecules are referred to as intermolecular forces.
 

 2. 

When the molecules of gases are heated, the average kinetic energy of the molecules increases.
 

 3. 

Zero on the Celsius scale is also known as absolute zero.
 

 4. 

Molarity is the number of moles of solute dissolved per liter of solution
 

Multiple Choice
Identify the letter of the choice that best completes the statement or answers the question.
 

 5. 

In the equation H2(g) + Cl2(g) 2HCl(g), one volume of hydrogen yields how many volumes of hydrogen chloride?
a.
1
c.
3
b.
2
d.
4
 

 6. 

Equal volumes of diatomic gases under the same conditions of temperature and pressure contain the same number of
a.
protons.
c.
molecules.
b.
ions.
d.
Dalton's "ultimate particles."
 

 7. 

The standard molar volume of a gas at STP is
a.
22.4 L.
c.
g-mol wt/22.4 L.
b.
g/22.4 L.
d.
1 L.
 

 8. 

What is the volume occupied by 1 mol of oxygen at STP?
a.
11.2 L
c.
22.4 L
b.
16.0 L
d.
32.0 L
 

 9. 

What is the volume occupied by 1 mol of water vapor at STP?
a.
11.2 L
c.
22.4 L
b.
18.0 L
d.
33.6 L
 

 10. 

A 1.00 L sample of a gas has a mass of 1.25 g at STP. What is the mass of 1 mol of this gas?
a.
a little less then 1.0 g
c.
22.4 g
b.
1.25 g
d.
28.0 g
 

 11. 

What is the value of the gas constant?
a.
0.0821 mc011-1.jpg
c.
0.0281 mc011-2.jpg
b.
0.0281 L·atm
d.
0.0821 mol·K
 

 12. 

What is the pressure exerted by 1.2 mol of a gas with a temperature of 20.˚C and a volume of 9.5 L?
a.
0.030 atm
c.
3.0 atm
b.
1.0 atm
d.
30. atm
 

 13. 

The equation for the complete combustion of methane is CH4(g) + 2O2(g) 2H2O(g) + CO2(g). If 50 L of methane at STP are burned, what volume of carbon dioxide will be produced at STP?
a.
16.6 L
c.
50 L
b.
25 L
d.
100 L
 

 14. 

If the temperature of a closed liquid-vapor equilibrium system is raised, its vapor pressure
a.
decreases.
c.
remains the same.
b.
increases.
d.
shows no correlation.
 

 15. 

At about what temperature does water reach its maximum density?
a.
0˚C
c.
4˚C
b.
2˚C
d.
6˚C
 

 16. 

Which of the following is an electrolyte?
a.
sodium chloride
c.
water
b.
sugar
d.
glass
 

 17. 

Raising solvent temperature causes solvent-solute collisions to become
a.
less frequent and more energetic.
c.
less frequent and less energetic.
b.
more frequent and more energetic.
d.
more frequent and less energetic.
 

 18. 

What is the molarity of a solution that contains 0.202 mol KCl in 7.98 L solution?
a.
0.0132 M
c.
0.459 M
b.
0.0253 M
d.
1.363 M
 

 19. 

What is the molality of a solution that contains 31.0 g HCl in 5.00 kg water?
a.
0.062 m
c.
0.170 m
b.
0.425 m
d.
15.5 m
 

 20. 

How many moles of ions are produced by the dissociation of 1 mol of MgCl2?
a.
0
c.
2 mol
b.
1 mol
d.
3 mol
 

 21. 

Which compound dissociates to produce the ions Ca2+(aq) and NO3(aq)?
a.
CaNO3(s)
c.
Ca(NO3)2(s)
b.
Ca2NO3
d.
Ca2(NO3)3
 

 22. 

A water solution containing an unknown quantity of a nonelectrolyte solute has a freezing point of –0.665˚C. What is the molal concentration of the solution if Kf = –1.86˚C/m?
a.
0.010 m
c.
0.358 m
b.
0.355 m
d.
2.66 m
 

 23. 

Which is NOT a value equal to 1 atm of pressure?
a.
760 torr
c.
101.3 kPa
b.
1 psi
d.
760 mmHg
 

 24. 

A sample of three mixed gases is at 632.0 mmHg. If the partial pressure of CO2 is 124.3 mmHg and the partial pressure of N2 is 461.9 mmHg, what is the partial pressure of O2?
a.
760 mmHg
c.
173.8 mmHg
b.
45.8 mmHg
d.
128 mmHg
 

 25. 

Which is an intermolecular force?
a.
ionic bond
c.
hydrogen bond
b.
covalent bond
d.
metallic bond
 

 26. 

Which is the triple point of this substance?
mc026-1.jpg
a.
88° C, 0.95 atm
c.
150° C, 1.45 atm
b.
110° C, 1.00 atm
d.
36° C, 2.1 atm
 

 27. 

Which is the point at which this substance will boil at normal atmospheric pressure?
a.
88°C, 0.95 atm
c.
110°C, 1.00 atm
b.
100°C, 0.95 atm
d.
0°C, 0.18 atm
 

 28. 

Hospital patients are administered oxygen from an pressurized hyperbaric oxygen chamber. 600.0 L of oxygen is compressed in a cylinder at 160.0 atm. What volume of oxygen can a cylinder supply at the given pressure?
mc028-1.jpg
a.
11 L
c.
11 x 103 L
b.
32 L
d.
32 x 103 L
 

 29. 

At an ocean depth of 10.0 m, a diver’s lung capacity is 2.40 L. The air temperature is 32.0°C and the pressure is 101.30 kPa. What is the volume of the diver’s lungs at the same depth, at a temperature of 21.0°C and a pressure of 141.20 kPa?
a.
1.12 L
c.
1.78 L
b.
1.66 l
d.
4.86 L
 

 30. 

What volume does .0685 mol of gas occupy at STP?
a.
.3707 mol
c.
1.53 L
b.
.7515 mol
d.
3.06 L
 

 31. 

What volume of oxygen is needed to react with solid sulfur to form 6.20 L of sulfur dioxide?
a.
6.20 L
c.
12.4 L
b.
7.20 L
d.
99.2 L
 

 32. 

The erratic movement of colloid particles is called:
a.
Brownian motion
c.
Slow motion
b.
Colloidal motion
d.
Suspended motion
 

Short Answer
 

 33. 

If 0.85 g of gas at 4.0 atm of pressure dissolves in 1.0 L of water at 25°C, how much will dissolve in 1.0 L of water at 1.0 atm of pressure and the same temperature?
 

Problem
 

 34. 

What is the molarity of a methanol solution that contains 25 g of methanol in 3.5 L of a solution? The molar mass of methanol is 32 g/mol.
 

 35. 

A 41.0-mL barium hydroxide solution of molarity 3.41 M is diluted with water to form 279 mL of the solution. Calculate the molarity of the solution.
 



 
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